Not to get in over my head but I was just suggesting that it’s the same molecules in the fruits of the pepper and vine. As to how much are in one grape variety vs another, I don’t know. From experience, I think Wes has a good point. All of the so-called Carmenet family has those to some degree. But sunlight makes a big difference in how many remain in the fruit. Linda Bisson did a lot of work on this and it’s largely because of her that we understand how canopy management can really make a difference.
In Chile in particular, they planted the wrong grapes or the wrong sites and managed to get over-ripe and jammy as well as green qualities and those wines to me, were horrible. They’ve improved dramatically over the past 20 years though, and that observation no longer holds true.
I was once at a large tasting and two producers of Cab Franc were in attendance - Bernard Baudry and Pam Starr. Both produce varietal Cab Franc and I like both, but they’re worlds apart stylistically. I introduced the two and they tasted each other’s wines. There’s no way that Baudry could produce a CF like they do in Napa, no matter how hard he tried. And I doubt that Pam’s site could get anything like the style Baudry gets in the Loire. Baudry’s is what you consider CF when you’re thinking about leaner wines with bell pepper notes, and since the grape originated somewhere over there, maybe that’s a “correct” version of the variety. But Pam produces what you get when you transplant that grape into a different environment that has more sun and less dampness and has a longer ripening period. It just becomes a different grape and I suspect that even if they were to use the same clones, the wines would be vastly different because of the wine making style, the environment, and also, as Wes says, the market acceptance.
CF is interesting to me because it is so different in so many different places - WA, MI, NY, CA, all produce it and in each state there are many different iterations. Argentina, Chile, France, Italy, Hungary, Austria, Slovenia and Spain also produce it and again, it’s different in each country and from each site. Not all versions are comparable to those from the Loire or even Bordeaux.
The levels you find will have a lot to do with decisions made in the vineyard, and to a lesser extent, in the cellar.
Things that matter are vegetative growth - more shoots and leaves mean more pyrazines; soil moisture - more moisture increases vegetive growth; leaf maturity - older leaves produce less; fruit exposure to light - more exposure means fewer pyrazines; crop load and rate of fruit maturation; temperature - warmer temps cause malic acid and pyrazines to break down faster; and whether the fruit ripened evenly. Also, the flavors can come from other compounds besides the pyrazines. It’s formed early and breaks down following véraison. But that’s in the fruit. It’s also formed in the leaves and carried to the fruit. That stops obviously when the stem lignifies.
If there are leaves and stems in the mix when grapes are crushed, that also increases the amount of pyrazines, particularly if there are younger leaves involved.
At the end of ripening, it degrades faster than it accumulates, so longer ripening times will reduce it as well.
Of course, the taste of rocks isn’t affected by any of this!!