You only truly learn something in minute detail if it really matters intensely to you in some way. if your life depended upon your sense of smell, or if you would starve to death, or freeze to death, or poison yourself without a reliable sense of smell, you bet you’d learn to differentiate key things in a reliable and reproducible way.
This.
And what Andrew said above.
Humans are actually pretty good at smelling and tasting, but we don’t really pay all that much attention. I have tasted wine with a lot of people and the fact that they like it doesn’t mean they’re very good tasters. That includes many people who collect the stuff and write long and florid tasting notes.
To learn it you have to pay attention. And that requires building a memory bank. We can definitely do it - it’s what helped us survive when we were hunter gatherers. Sight obviously matters a lot more to us today, but we are actually pretty good at smell/taste memory too, as long as we pay attention in the same way we do to sight. And the mental patterns are pretty similar too - it’s pattern recognition in each case, at least according to brain studies.
I think that whether we have the words to describe the sensation with precision matters somewhat less. I don’t know what gives that specific green aroma to a tomato leaf, even though I’ve read the chemical name before, but having grown tomatoes I can recognize it. And there is a slightly different aroma associated with each of the four or five kinds of basil I used to grow. Once it sticks in your head, you can remember the distinction between Thai basil and that purple one with the thick leaves that dies fast, whatever the name is. But if you haven’t paid any attention, or haven’t had all of them side by side, you just describe the whole thing as “basil”.
It’s why we call things “red” fruit or "black"fruit or “rose”, none of which really mean much since there are a hundred of roses that all smell different, and there are dark fruits that can be very bitter, sour, or sweet or all of those at once. But if you had boysenberries, blueberries, and black currants side by side, they’re all dark and all different. And then there are the specific cultivars on top of that.
You need exposure + close attention + memory and you’ll do fine. Lots of wine tasters just galp down food and drink all day and then when they open a bottle of wine they obsess over a glass shape and suddenly try to pay all kinds of attention but they really don’t make paying attention part of their lives. It’s more or less like spending all week playing video games and eating granola bars and then deciding to get up and run a 5K race. Good luck with that.