Hi Brian,
You can’t really isolate these things. Trying to view TA and pH separately from a specific wine is kind of like saying, “a golfer has a driver and a short wedge, if he uses the short wedge 7 times and the driver 14 times, what is the round like? If he uses the wedge 4 times and the driver 16 times what is the difference?” Without seeing the course, you can’t know.
Generally speaking:
If pH goes down, then TA has to move upwards.
To move pH down and have TA remain constant, you are talking about two different wines.
To have pH go down, how it will translate organoleptically, you would need to know what acid was causing the pH to go down.
If you look at this as a multi-verse where the same wine in one universe is 3.2 pH and 7.0g TA and in another is 3.1 pH and 7.0g TA, you need to know which, of the multitude of acid combinations (between tartaric, malic, and va) that caused the decrease in pH to occur. Because there will be different aromatics to most of the different permutations.
Generally speaking, the type of acid is more important than the numerical change. And all of the changes in aromatics are affected by the amount of glycerin, tannin, dry extract, alcohol, etc.
I do know that higher acids can really unlock the nose of a wine (from bench trials with acid additions), but how we would percevive that change would dramatically change depending upon the abv of the wine you are talking about.
Frankly, trying to reduce wine perception to define specific variables, IN MY OPINION, is almost always a fool’s errand. You can’t do it. And when we try to force that to happen the common result, because humans are rarely afraid of a fool’s errand, is bad information that gets applied as if it were fact. I post this because I see this type of conclusion drawn routinely.
Like Tyrion Lannister, we like to know things. But in wine perception it’s best to stay a blank slate and listen to the wine. Again, just my opinion.