I’ve finally found a little time to read more of Jamie’s book. I’ve only scratched the surface, and my (distant) high school chemistry isn’t much help with the more technical parts. But the chapter on wine flavor chemistry is fascinating. Here are some highlights, some of which are counter-intuitive.
• Some grapes have “impact compounds” – volatile chemicals that correspond to specific aromas and give that grape their character. These include compounds that yield green/grassy/green pepper; linalool, which gives the floral/citrus scent to muscat; one that yields the flowery, rosy smell of gewurtz; and one that produces the pepper in syrah; and tropical fruits/passion fruit/grapefruit (e.g., sauvignon blanc). I think we all know how easy it is to recognize a grassy sauvignon blanc or the orange peel of a muscat.
• Not all grapes have impact compounds. This may explain the lack of a distinct fruit profile for grapes like chardonnay.
• Both (a) low-level volatile compounds (at too low a level to be perceived) and (b) non-volatile compounds (things we can’t smell or taste) can markedly affect the perception of volatile compounds, including impact compounds. Add or eliminate these in the lab and it can alter the smells and tastes of the wine.
• Alcohol increases the solubility of volatile compounds and aromas therefore decrease as alcohol increases. Past 14.5%, there is a sharp fall-off in aromas.
This is quite counter-intuitive to me. I had assumed that alcohol might accentuate aromas. But, on reflection, it squares with the fact that some of the most aromatic wines, such as red Burgundy and nebbiolo, are very high in acid.
• (In a magazine article a year or so ago, Jamie explained that sweet wines are more intense aromatically for the opposite reason: The wine is relatively (or completely) saturated with dissolved sugar. That causes the volatile aroma compounds to evaporate quickly with the wine is opened. This explains the night-and-day difference in aromas between sweet and dry rieslings, even when picked at similar sugar levels.)
• Acid levels affect color: High pH/low acid wines are darker (e.g., big cabs, syrahs, zins), while the pigments in high acid wines tend to be lighter (think nebbiolo, pinot, tempranillo). Of course, the chemistry of the individual grape types is important, too.
• Someplace in the book that I can’t now find he says that acid/pH also affects the fruit profile. Higher acid/lower pH wines are perceived as red-fruited, while lower acid/higher pH wines are more dark-fruited. I’m not clear on whether this is simply a reflection of riper red grapes tending to be darker in flavors. But I think he was sayting that the red/dark scale is partly a reflection simply of acid levels.
Anyway, lots of interesting, explanatory stuff there that should be of interest to Berserkers.
I still haven’t found a section explaining the pros and cons of decanting.