But Thomas, that wouldn’t have applied in Tuscany or Rioja where they weren’t using aromatic grapes like Viognier. I haven’t read what Johnson wrote, but he may have been relating a story. I’d be surprised if he were passing it on as fact.
If you can find it, here’s an old paper: Robinson, G.M., and R. Robinson. A survey of anthocyanins. I.
Biochem. J. 25:1687-1705 (1931).
Not particularly wine-related, but in the study, they ranked a lot of different coloring co-factors by their ability to shift the color to blue. The gist of it is that you have coloring molecules (pigments) and other molecules that have nothing to do with color but that bind with pigments and cause the pigments to exhibit deeper and richer colors.
It’s not at all limited to wine - it’s what happens in flowers and other things. In fact, unlike wine, there’s actually been a lot of research into color because people have spent hundreds of millions over the years to produce a blue rose. It will likely never exist because of the acidic nature of the plant, but who knows.
In grapes, you have certain molecules that produce color, and some grapes have a lot of those, but just like “minerals” in the soil, there’s no correlation between the presence of something in the environment and the presence of that in your finished wine. All kinds of variables come into play - pH, temperature, etc.
So you can have anthocyanins, tannins, etc. but whether or not you can extract them from the skins and get them into your wine is a different story. So you add something that helps you extract. In this case it’s some white wine. You’re not necessarily adding it for aroma or flavor. And you need only very small amounts. Again, complete speculation here, but I’d imagine that the use of five percent or less came about because people didn’t see better results after that amount but they started picking up aromatics and non-Syrah notes.
And in fact, science has verified that as well. The old guys seem to have been on to something because at concentrations over 15%, the color enhancement and stabilization effects of the Viognier were reduced. Not sure why but there’s speculation that it may be through dilution?
The scientific bullshit was always there and could be observed by anybody. It just took guys like Newton and Kepler to explain what everyone was observing.
It’s true that people probably had no idea what the chemistry was behind some of the things they observed. They just noticed things and experimented until they got an acceptable result. Science later explained why they were right.